Think you should discount using E5 then, not really an option.
Normal pump fuel is 95 octane, by adding a good octane booster, ie. lucas or NF you'll gain 2/3 ron so fuel will be 97 or 98octane.
No known issues with cars running octane booster, mines been mapped with booster for last 3 years and no problem. The only issue is booster will shorten the life of your spark plugs, I've no technical knowledge so can't explain why, but it leaves a deposit on the tip of your spark plug which shortens the life of them.